Mediterranean water hot enough now to form carbonate crystals, possibly centered on micro plastics


by Matt Simon for Wired, OCT 4, 2022 7:00 AM

The Mediterranean Sea Is So Hot, It’s Forming Carbonate Crystals

In the rapidly warming Eastern Mediterranean, water stratifies into layers, like a cake. That’s allowing carbon-spewing crystals to form.

Mediterranean Sea

    IF YOU STAND on the coast of Israel and gaze out across the Mediterranean Sea, you’ll spy deep-blue, calm waters that have sustained humans for millennia. Beneath the surface, though, something odd is unfolding: A process called stratification is messing with the way the sea processes carbon dioxide.

    Think of this part of the Mediterranean as a cake made of liquid, essentially. Fierce sunlight heats the top layer of water that sits on cooler, deeper layers below. Out in the open ocean, where water temperatures are lower, CO2 dissolves in saltwater—which is what allows Earth’s seas to collectively absorb a quarter of the carbon emissions that humans pump into the atmosphere. But as the eastern Mediterranean Sea heats up in the summer, it can no longer absorb that gas and instead starts releasing it.

    It’s the same thing that happens in a bottle of soda that is carbonated with carbon dioxide. “You usually keep it cold, so the dissolved gasses will stay dissolved,” says Or Bialik, a geoscientist at the University of Münster in Germany. “If you leave it in your car for a while and try to open it, all the gasses are going to pop out at once, because when it warms, the capacity of the fluid to hold CO2 goes down.” Boomfizz, you’ve got a mess on your hands. 

    In the Eastern Mediterranean, this dynamic is rather more consequential for the climate than a sticky car interior, as the sea begins burping up great quantities of CO2 that the water can no longer hold. And Bialik and his colleagues have discovered that these warming, stratifying waters teem with a second carbon problem: The team recently caught aragonite crystals in sediment traps. Aragonite is a form of calcium carbonate, which oceanic creatures like snails use to build their shells. Except in the increasingly hot Eastern Mediterranean, the aragonite is forming abiotically. That’s another sign that the water is getting so warm that it’s releasing its carbon load.

    In these hot, shallow, stable waters, the fluid on top doesn’t mix much with the underlying colder layers, in contrast to deeper parts of the ocean, where upwelling brings up cooler H2O. “The conditions are so extreme that we can definitely generate calcium carbonate chemically from these waters, which was kind of a shock for us,” says Bialik, who coauthored a recent paper describing the discovery in the journal Scientific Reports. (He did the research while at the University of Malta and University of Haifa.) “It’s basically like a beaker that sits there for a very long time, and it’s long enough to get these reactions going and start generating these crystals.”

    It’s like the experiments you might have done as a kid with sugar crystals. You added a bunch of sugar to water, saturating it. Nothing happened until you dropped in a string, which allowed the sugar to precipitate into fat clusters that clung to the string. Similarly, when the Mediterranean heats up and stratifies, it’s saturated with carbonate. How exactly the aragonite reactions get going, Bialik and his colleagues can’t yet say, but they may start with nuclei like specks of dust blown off nearby land, upon which the layers of aragonite build into crystals—a very tiny version of the string in the sugar water.

    It’s also worth noting that the Mediterranean Sea is one of the most microplastic-polluted water bodies in the world: In 2020, scientists reported finding 2 million particles in a single square meter of sediment that was only 5 centimeters thick. Whether aragonite crystals are forming around microplastics floating in the water column, Bialik doesn’t know. “They could probably form around any nucleation center,” says Bialik. “I suspect that microplastics may also be a possible one. But as scientists love to say, more research is needed.” 

    What Bialik and his colleagues can say, though, is that as these crystals form, they release CO2. So much so, Bialik calculates, that they account for perhaps 15 percent of the gas that the Mediterranean Sea emits to the atmosphere.

    As the sea warms up and loses its CO2, both from the water belching it up and from the proliferating crystals, its acidity actually goes down. This is the opposite process from the one that’s causing widespread ocean acidification: As humans spew more CO2 into the atmosphere, the oceans absorb more of it, and the ensuing chemical reaction raises acidity. Acidification makes it harder for organisms like corals and snails (which are known collectively as calcifiers), to build shells or exoskeletons out of calcium carbonate. But as the Mediterranean warms and releases its absorbed carbon back into the atmosphere, it gets more basic, reversing that acidification.

    That should be great for the calcifiers, right? Not necessarily. “Many of them have specific temperature ranges in which they can build their shells—not too hot, not too cold,” says Bialik. So even if the sea is getting less acidic as it warms, that heat stresses these organisms in a different way. (Not to mention the stress of being constantly exposed to extreme levels of microplastics.)

    It’s not clear whether aragonite crystals are forming in more places around the world. Scientists are already aware of “whiting events,” in which calcium carbonate precipitates in much more obvious ways, turning the waters around the Bahamas and in the Persian Gulf a milky color. In the Eastern Mediterranean, there wasn’t an obvious whiting event to clue in Bialik and his colleagues. Instead, they stumbled upon the crystals in their sediment traps.

    “This is a somewhat unique area with a variety of conditions that have to happen to make this work,” says marine chemist Andrew Dickson of the Scripps Institution of Oceanography, who wasn’t involved in the research. “The question then is, to what degree is that environment really special, or is it common around the oceans? And I don’t have a clear picture of that in my mind.”

    It may be that the conditions in the eastern Mediterranean aren’t replicated in many other places, so Dickson is leaning toward the idea that this may not be particularly common. But Bialik points out that wherever it may be happening, it could be causing a climate problem: Aragonite crystal formation may mess with the water’s ability to absorb atmospheric CO2, thus interfering with how the ocean reduces levels of the planet-heating gas. 

    “I won’t say we fully understand this yet and fully understand what governs it—when it turns on and when it shuts down,” says Bialik. “We didn’t even think this process occurs on this scale in open waters, in normal marine conditions. And so we still have a lot that we need to understand about it.”

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